Wear and Friction Effects on Engine Materials of N-Butanol in Ultra-Low Sulfure Diesel Mixtures
Gustavo Molina, John L. Morrison, Valentin Soloiu, Cesar Carapia
Abstract
Gustavo Molina, John L. Morrison, Valentin Soloiu, Cesar Carapia
Abstract
The lack of the sulfur beneficial lubricity in ultra-low sulfur diesel (ULSD) may lead to premature wear and failure of diesel-fuel systems. Mixing of small percentages of, for instance, biodiesels and other biofuels is typically used to add lubricity in ULSD. N-butanol has been recently proved to mix in or replace diesel without compromising engine combustion performance. But anti-wear properties of mixing N-Butanol in ULSD have not previously been studied. This paper presents a tribology study on the effects of N-Butanol in ULSD in a steel-on steel sliding contact. The research work employed a pin on disk tribometer for friction-force data acquisition, and wear was measured by specimen weight-change. The wear results and the friction force evolution observed in tests indicate that the dilutions of ULSD with N-Butanol can lead to a reduction of wear and that there is an optimum rate of dilution, of around 25% of N-Butanol in ULSD, that minimizes wear and increases the mixture lubricity as compared to those of both pure ULSD and pure N-Butanol.
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The lack of the sulfur beneficial lubricity in ultra-low sulfur diesel (ULSD) may lead to premature wear and failure of diesel-fuel systems. Mixing of small percentages of, for instance, biodiesels and other biofuels is typically used to add lubricity in ULSD. N-butanol has been recently proved to mix in or replace diesel without compromising engine combustion performance. But anti-wear properties of mixing N-Butanol in ULSD have not previously been studied. This paper presents a tribology study on the effects of N-Butanol in ULSD in a steel-on steel sliding contact. The research work employed a pin on disk tribometer for friction-force data acquisition, and wear was measured by specimen weight-change. The wear results and the friction force evolution observed in tests indicate that the dilutions of ULSD with N-Butanol can lead to a reduction of wear and that there is an optimum rate of dilution, of around 25% of N-Butanol in ULSD, that minimizes wear and increases the mixture lubricity as compared to those of both pure ULSD and pure N-Butanol.
Key concepts: Ultra-low-sulfur diesel, Lubricity, Diesel fuel, Lubrication, Materials science, Tribology, Butanol, Tribometer