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2022•Dalton TransactionsRequires access

Lewis acid–base adducts of Al(N(C 6 F 5 ) 2 ) 3 and Ga(N(C 6 F 5 ) 2 ) 3 – structural features and dissociation enthalpies

Julius F. Kögel, Denis A. Sorokin, Martin Scott, Klaus Harms, Daniel Himmel, Ingo Krossing, Jörg Sundermeyer

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Abstract

Herein we present the molecular structures of six neutral Lewis acid–base adducts of the Lewis superacid Al(N(C 6 F 5 ) 2 ) 3 and its higher homolog Ga(N(C 6 F 5 ) 2 ) 3 with the electron pair donors MeCN, CN t Bu, THF and PMe 3 .

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Herein we present the molecular structures of six neutral Lewis acid–base adducts of the Lewis superacid Al(N(C 6 F 5 ) 2 ) 3 and its higher homolog Ga(N(C 6 F 5 ) 2 ) 3 with the electron pair donors MeCN, CN t Bu, THF and PMe 3 .

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Available abstract

Herein we present the molecular structures of six neutral Lewis acid–base adducts of the Lewis superacid Al(N(C 6 F 5 ) 2 ) 3 and its higher homolog Ga(N(C 6 F 5 ) 2 ) 3 with the electron pair donors MeCN, CN t Bu, THF and PMe 3 .

Key concepts: Lewis acids and bases, Adduct, Chemistry, Fluoride, Crystal structure, Superacid, Chloride, Dissociation (chemistry)

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Lewis acid–base adducts of Al(N(C 6 F 5 ) 2 ) 3 and Ga(N(C 6 F 5 ) 2 ) 3 – structural features and dissociation enthalpies — Research Paper | ScholarLens