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ChemInform Abstract: Bonded vs. Nonbonded Electron Transfers in Molten Salts: Characterization and Rates of Formation of the Radical Cations and Dications of Phenoxazine and Phenothiazine and Behavior of the M(2,2′‐bipyridine)32+/3+ (M: Fe, Ru, Os) Complexes in SbCl3‐Rich Media.

David M. Chapman, A. C. Buchanan, Gregory P. Smith, G. Mamantov

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Abstract

Abstract The electrochemical and homogeneous oxidations of phenoxazine and phenothiazine to their highly persistent radical Cations, and dications are studied in anhydrous SbCl3 ‐ AlCl3‐ N‐(l‐butyhpyridinium Chloride mixtures at 23‐27°C. The progress of these oxidations is followed by fast optical spectroscopy.

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Abstract The electrochemical and homogeneous oxidations of phenoxazine and phenothiazine to their highly persistent radical Cations, and dications are studied in anhydrous SbCl3 ‐ AlCl3‐ N‐(l‐butyhpyridinium Chloride mixtures at 23‐27°C. The progress of these oxidations is followed by fast optical spectroscopy.

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Available abstract

Abstract The electrochemical and homogeneous oxidations of phenoxazine and phenothiazine to their highly persistent radical Cations, and dications are studied in anhydrous SbCl3 ‐ AlCl3‐ N‐(l‐butyhpyridinium Chloride mixtures at 23‐27°C. The progress of these oxidations is followed by fast optical spectroscopy.

Key concepts: Phenoxazine, Phenothiazine, Anhydrous, Chemistry, Electrochemistry, Homogeneous, Chloride, Radical ion

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ChemInform Abstract: Bonded vs. Nonbonded Electron Transfers in Molten Salts: Characterization and Rates of Formation of the Radical Cations and Dications of Phenoxazine and Phenothiazine and Behavior of the M(2,2′‐bipyridine)32+/3+ (M: Fe, Ru, Os) Complexes in SbCl3‐Rich Media. — Research Paper | ScholarLens