2021Chemistry LettersRequires access

Propane Dehydrogenation Catalysis of Titanium Hydrides: Positive Effect of Hydrogen Co-feeding

Shunsaku Yasumura, Yuxiang Wen, Takashi Toyao, Yasuharu Kanda, Ken‐ichi Shimizu, Zen Maeno

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Abstract

Abstract This study investigated non-oxidative propane dehydrogenation over TiH2. It was found that H2 co-feeding positively affected dehydrogenation, improving the propylene formation rate. In situ spectroscopic characterization of TiH2 in the presence of H2 indicated that partially dehydrogenated titanium hydrides are active for dehydrogenation.

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Abstract This study investigated non-oxidative propane dehydrogenation over TiH2. It was found that H2 co-feeding positively affected dehydrogenation, improving the propylene formation rate. In situ spectroscopic characterization of TiH2 in the presence of H2 indicated that partially dehydrogenated titanium hydrides are active for dehydrogenation.

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Available abstract

Abstract This study investigated non-oxidative propane dehydrogenation over TiH2. It was found that H2 co-feeding positively affected dehydrogenation, improving the propylene formation rate. In situ spectroscopic characterization of TiH2 in the presence of H2 indicated that partially dehydrogenated titanium hydrides are active for dehydrogenation.

Key concepts: Chemistry, Dehydrogenation, Propane, Catalysis, Hydrogen, Titanium, Inorganic chemistry, Organic chemistry

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