1988•OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)Requires access

Concentration oscillations of zinc tetra-4-tert-butylphthalocyanine in ethanol in pulsed radiolysis

N.P. Chelnakov, V.I. Tupikov, K. E. Danilov

Abstract

Deaerated solutions of monomeric zinc tetra-4-tert-butylphthalocyanine (ZnPC) in ethanol were studied by spectrophotometry directly during /gamma/ and pulsed microsecond radiolysis. It was shown that the ZnPC monoanion is formed on decomposition of the extracomplex of ZnPC with the hydroxyethyl radical and subsequent conversion of the monoanion into the starting ZnPC is accompanied by concentration oscillations. A model system of reactions is proposed which describes the experimental characteristics.

About this research paper

What this paper is about

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Key concepts: Radiolysis, Microsecond, Zinc, Chemistry, Tetra, Ethanol, Decomposition, Photochemistry