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2004•Acta Crystallographica Section E Structure Reports OnlineRequires access

catena-Poly[[aqua(phenanthroline)zinc(II)]-μ-cyclohexanedicarboxylato]

Wenhua Bi, Daofeng Sun, Rong Cao, Yanqin Wang

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Abstract

The title complex, [Zn(C8H10O4)(C12H8N2)(H2O)]n, has a chain structure. The central ZnII ion is coordinated by four water and carboxylate O atoms and two N atoms from 1,10-phenanthroline. All the cyclo­hexane­di­carboxyl­ate ligands are in an e,a-cis-conform­ation and each is linked to two ZnII ions in chelating and monodentate modes. The most interesting feature of the structure is that it possesses a 21 helical axis in the chain.

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What this paper is about

The title complex, [Zn(C8H10O4)(C12H8N2)(H2O)]n, has a chain structure. The central ZnII ion is coordinated by four water and carboxylate O atoms and two N atoms from 1,10-phenanthroline. All the cyclo­hexane­di­carboxyl­ate ligands are in an e,a-cis-conform­ation and each is linked to two ZnII ions in chelating and monodentate modes. The most interesting feature of the structure is that it possesses a 21 helical axis in the chain.

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Available abstract

The title complex, [Zn(C8H10O4)(C12H8N2)(H2O)]n, has a chain structure. The central ZnII ion is coordinated by four water and carboxylate O atoms and two N atoms from 1,10-phenanthroline. All the cyclo­hexane­di­carboxyl­ate ligands are in an e,a-cis-conform­ation and each is linked to two ZnII ions in chelating and monodentate modes. The most interesting feature of the structure is that it possesses a 21 helical axis in the chain.

Key concepts: Denticity, Carboxylate, Phenanthroline, Zinc, Chemistry, Chelation, Ion, Crystallography

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