The Enantiomer Separations of Allethrone and Propargyllone Using Two Long Chain Acylated β-Cyclodextrin Derivatives as CGC Capillary Stationary Phases
Xue, Yan, Shi, Hong, Chao, Guo, Zhen, Qiao Qiao, Cong Cong, Hou, Min Min, Wang
Abstract
Xue, Yan, Shi, Hong, Chao, Guo, Zhen, Qiao Qiao, Cong Cong, Hou, Min Min, Wang
Abstract
Using two β-cyclodextrin derivatives (CDs) with long chain of acyl groups as chiral stationary phases (CSPs) of capillary gas chromatography (CGC), the enantiomers of racemic allethrone and propargyllone were well resolved after derived with acetyl chloride. The enantiomer excess values (e.e.%) of 1S-allethrone and 1S-propargyllone were also determined successfully using these CDs.
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Using two β-cyclodextrin derivatives (CDs) with long chain of acyl groups as chiral stationary phases (CSPs) of capillary gas chromatography (CGC), the enantiomers of racemic allethrone and propargyllone were well resolved after derived with acetyl chloride. The enantiomer excess values (e.e.%) of 1S-allethrone and 1S-propargyllone were also determined successfully using these CDs.
Key concepts: Enantiomer, Cyclodextrin, Chemistry, Capillary gas chromatography, Chromatography, Capillary action, Gas chromatography, Chloride