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2006•Chinese Chemical LettersRequires access

Studies on the Simultaneous Synthesis of Dimethyl Carbonate and Poly (Ethylene Terephthalate): I. Catalytic Activity of Metal Acetate in Transesterification of Ethylene Carbonate with Dimethyl Terepht

Dan Zhang, Shuyong Jia, Yue Wang, Jie Yao, Yi Zeng, Gongying Wang

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Abstract

A novel direct method for preparation of dimethyl carbonate and poly (ethylene terephthalate) from ethylene carbonate and dimethyl terephthalate has been demonstrated in the presence of metal acetate catalysts, lithium acetate dihydrate showed highest catalytic activity with 47.9% yield of dimethyl carbonate. This method was a green chemical process.

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What this paper is about

A novel direct method for preparation of dimethyl carbonate and poly (ethylene terephthalate) from ethylene carbonate and dimethyl terephthalate has been demonstrated in the presence of metal acetate catalysts, lithium acetate dihydrate showed highest catalytic activity with 47.9% yield of dimethyl carbonate. This method was a green chemical process.

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Available abstract

A novel direct method for preparation of dimethyl carbonate and poly (ethylene terephthalate) from ethylene carbonate and dimethyl terephthalate has been demonstrated in the presence of metal acetate catalysts, lithium acetate dihydrate showed highest catalytic activity with 47.9% yield of dimethyl carbonate. This method was a green chemical process.

Key concepts: Dimethyl carbonate, Ethylene carbonate, Transesterification, Catalysis, Ethylene, Dimethyl terephthalate, Carbonate, Chemistry

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Studies on the Simultaneous Synthesis of Dimethyl Carbonate and Poly (Ethylene Terephthalate): I. Catalytic Activity of Metal Acetate in Transesterification of Ethylene Carbonate with Dimethyl Terepht — Research Paper | ScholarLens