Rapid and Mild Synthesis of an NHC-Coordinated Bis(trimethylsilyl)silylene via Elimination of Halotrimethylsilane

Base-coordinated silylenes are often used as electron-donating ligands for metal complexes and low-coordinate species of main group elements. However, the synthesis routes to base-coordinated silylenes remain limited. Herein, we report a rapid and mild reaction providing NHC-coordinated bis(trimethylsilyl)silylene 2, which includes the coordination of 1,3,4,5-tetramethylimidazol-2-ylidene (IMe 4 ) to (Me 3 Si) 3 SiX ( 1, X= Cl, Br, and I) and the subsequent elimination of the corresponding Me 3 SiX assisted by another IMe 4 molecule. Silylene 2 undergoes not only the coordination to BPh 3 and the addition reactions with 2,3-dimethylbutadiene and Me 3 SiI but also an unprecedented substitution reaction with (Me 3 Si) 3 SiI affording (Me 3 Si) 3 Si-substituted IMe 4 -coordinated silylene 6 .