2021Solid Fuel ChemistryRequires access

Application of Hydrothermal Carbonization to Improve the Energy Properties of Peat

K. O. Krysanova, A. Yu. Krylova, В. М. Зайченко

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Abstract

Abstract The influence of the process conditions of hydrothermal carbonization (temperature, process duration, the presence of a catalyst (citric acid), and the raw material/water ratio) on the properties of hydrochar obtained from peat was studied. The following regularities were found: the weight and energy yields of the hydrochar decreased with the temperature and reaction time. An increase in the reaction temperature from 170 to 230°С contributed to an increase in the calorific value (from 23.86 to 26.8 MJ/kg for the gross calorific value and from 22.26 to 25.02 MJ/kg for the net calorific value). An increase in the reaction time from 1 to 6 h also led to an increase in the calorific value (from 22.72 to 24.61 MJ/kg for the gross calorific value and from 24.61 to 23.20 MJ/kg for the net calorific value). The addition of a catalyst increased the gross and net calorific values of hydrochar by 6 and 6.2%, respectively.

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What this paper is about

Abstract The influence of the process conditions of hydrothermal carbonization (temperature, process duration, the presence of a catalyst (citric acid), and the raw material/water ratio) on the properties of hydrochar obtained from peat was studied. The following regularities were found: the weight and energy yields of the hydrochar decreased with the temperature and reaction time. An increase in the reaction temperature from 170 to 230°С contributed to an increase in the calorific value (from 23.86 to 26.8 MJ/kg for the gross calorific value and from 22.26 to 25.02 MJ/kg for the net calorific value). An increase in the reaction time from 1 to 6 h also led to an increase in the calorific value (from 22.72 to 24.61 MJ/kg for the gross calorific value and from 24.61 to 23.20 MJ/kg for the net calorific value). The addition of a catalyst increased the gross and net calorific values of hydrochar by 6 and 6.2%, respectively.

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Available abstract

Abstract The influence of the process conditions of hydrothermal carbonization (temperature, process duration, the presence of a catalyst (citric acid), and the raw material/water ratio) on the properties of hydrochar obtained from peat was studied. The following regularities were found: the weight and energy yields of the hydrochar decreased with the temperature and reaction time. An increase in the reaction temperature from 170 to 230°С contributed to an increase in the calorific value (from 23.86 to 26.8 MJ/kg for the gross calorific value and from 22.26 to 25.02 MJ/kg for the net calorific value). An increase in the reaction time from 1 to 6 h also led to an increase in the calorific value (from 22.72 to 24.61 MJ/kg for the gross calorific value and from 24.61 to 23.20 MJ/kg for the net calorific value). The addition of a catalyst increased the gross and net calorific values of hydrochar by 6 and 6.2%, respectively.

Key concepts: Hydrothermal carbonization, Heat of combustion, Chemistry, Carbonization, Catalysis, Raw material, Citric acid, Hydrothermal circulation

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