2021Journal of Quantitative Spectroscopy and Radiative TransferOpen access

Hyperfine components of rovibrational dipole transitions in HT and DT

Hubert Jóźwiak, Hubert Cybulski, Piotr Wcisło

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Abstract

We report a list of positions and intensities of 331 892 hyperfine components of all 18 585 rovibrational dipole transitions in the HT and DT isotopologues of molecular hydrogen. Apart from the study of hyperfine structure, we investigate the intensities of all rovibrational dipole transitions in the two isotopologues, which were not known prior to this work. The results presented here are crucial for a reliable interpretation of accurate measurements of rovibrational transition frequencies in the tritium-bearing isotopologues of hydrogen, which are useful for tests of quantum electrodynamics for molecules and searches for new physics beyond the Standard Model.

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We report a list of positions and intensities of 331 892 hyperfine components of all 18 585 rovibrational dipole transitions in the HT and DT isotopologues of molecular hydrogen. Apart from the study of hyperfine structure, we investigate the intensities of all rovibrational dipole transitions in the two isotopologues, which were not known prior to this work. The results presented here are crucial for a reliable interpretation of accurate measurements of rovibrational transition frequencies in the tritium-bearing isotopologues of hydrogen, which are useful for tests of quantum electrodynamics for molecules and searches for new physics beyond the Standard Model.

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Available abstract

We report a list of positions and intensities of 331 892 hyperfine components of all 18 585 rovibrational dipole transitions in the HT and DT isotopologues of molecular hydrogen. Apart from the study of hyperfine structure, we investigate the intensities of all rovibrational dipole transitions in the two isotopologues, which were not known prior to this work. The results presented here are crucial for a reliable interpretation of accurate measurements of rovibrational transition frequencies in the tritium-bearing isotopologues of hydrogen, which are useful for tests of quantum electrodynamics for molecules and searches for new physics beyond the Standard Model.

Key concepts: Rotational–vibrational spectroscopy, Hyperfine structure, Dipole, Atomic physics, Physics, Excited state, Quantum mechanics

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