A New Chain-like Copper(II) Polymer:[Cu(MOPIP)(BDC)]_n·0.5n(H_2O)
Liu Boa
Abstract
Liu Boa
Abstract
A metal-organic coordination compound formulated as [Cu(MOPIP)(BDC)]n·0.5n(H2O) 1 (MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline,BDC=1,4-benze Nedicar- boxylate) has been hydrothermally synthesized and structurally characterized by elemental analysis,thermogravimetric analysis,IR spectrum,and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system,space group P1,with a= 8.872(5),b=11.163(6),c=12.589(6),α=94.687(7),β=99.930(6),γ=103.074(7)°,V=1186.7(12)3,C28H19CuN4O5.5,Mr=563.01,Dc=1.576 g/cm3,μ(MoKα)=0.973 mm-1,F(000)=576,Z=2,the final R=0.0607 and wR=0.1618 for 3419 observed reflections (I2σ(I)).
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A metal-organic coordination compound formulated as [Cu(MOPIP)(BDC)]n·0.5n(H2O) 1 (MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline,BDC=1,4-benze Nedicar- boxylate) has been hydrothermally synthesized and structurally characterized by elemental analysis,thermogravimetric analysis,IR spectrum,and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system,space group P1,with a= 8.872(5),b=11.163(6),c=12.589(6),α=94.687(7),β=99.930(6),γ=103.074(7)°,V=1186.7(12)3,C28H19CuN4O5.5,Mr=563.01,Dc=1.576 g/cm3,μ(MoKα)=0.973 mm-1,F(000)=576,Z=2,the final R=0.0607 and wR=0.1618 for 3419 observed reflections (I2σ(I)).
Key concepts: Triclinic crystal system, Chemistry, Thermogravimetric analysis, Crystallography, Copper, Metal, Coordination polymer, Crystal structure