2021•Dalton TransactionsRequires access

Cyclopalladation of a ferrocene acylphosphine and the reactivity of the C–H activated products

Petr Vosáhlo, Jiří Schulz, Ivana Cı́sařová, Petr Štěpnička

Abstract

fragment and revealed variations in the Pd-donor distances dictated by an interplay between the trans influence and steric demands of the ligands surrounding Pd(ii). Moreover, some compounds were studied by DFT to rationalise their isomerisation equilibria and electrochemical properties, which were examined by cyclic voltammetry.

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Key concepts: Ferrocene, Reactivity (psychology), Chemistry, Medicinal chemistry, Physical chemistry, Electrochemistry, Electrode, Medicine