2021•Dalton TransactionsRequires access

HKUST-1 MOF in reline deep eutectic solvent: synthesis and phase transformation

Renata A. Maia, Benoît Louis, Stéphane A. Baudron

Open publisher page 47 citations

Abstract

(BTC)Cl also forms. It was unequivocally demonstrated that, upon heating in reline, HKUST-1 converts to the non-porous chloride-incorporating material. Hence, a novel feature of DES in MOF synthesis is uncovered: its role as a structure-directing agent, triggering the transformation between two different MOF structures.

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What this paper is about

(BTC)Cl also forms. It was unequivocally demonstrated that, upon heating in reline, HKUST-1 converts to the non-porous chloride-incorporating material. Hence, a novel feature of DES in MOF synthesis is uncovered: its role as a structure-directing agent, triggering the transformation between two different MOF structures.

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Available abstract

(BTC)Cl also forms. It was unequivocally demonstrated that, upon heating in reline, HKUST-1 converts to the non-porous chloride-incorporating material. Hence, a novel feature of DES in MOF synthesis is uncovered: its role as a structure-directing agent, triggering the transformation between two different MOF structures.

Key concepts: Deep eutectic solvent, Choline chloride, Eutectic system, Solvent, Phase (matter), Chloride, Materials science, Chemical engineering

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