2006Journal of Environmental Science InternationalOpen access

Adsorption Characteristics of Toluene Vapor According to Pore Size Distribution of Activated Carbon

Lee Song-Woo;Kwon Jun-Ho;Kang Jeong-Hwa;Na Young-Soo;An Chang-Doeuk;Yoon Young-Sam;Song Seung-Koo;

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Abstract

This study is to investigate the relationship between pore structures of activated carbons and adsorption characteristics of toluene vapor using dynamic adsorption method. The surface areas of below $10{\AA}$ in the pore diameter of activated carbons used in this experiment were in the range of 72 -93 % of total cumulative surface area and the toluene vapor equilibrium adsorption capacities were in the range of 350 - 390mg/g. Activated carbons having larger toluene adsorption capacity than the compared activated carbons had relatively pores in the pore diameter range of $7-10{\AA}$ . Linear relationship between equilibrium adsorption capacity and cumulative sur- face area was in the diameter range of over $7{\AA}$ . It was thought that toluene vapor was relatively well adsorbed on surfaces of pores of over $7{\AA}$ .

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This study is to investigate the relationship between pore structures of activated carbons and adsorption characteristics of toluene vapor using dynamic adsorption method. The surface areas of below $10{\AA}$ in the pore diameter of activated carbons used in this experiment were in the range of 72 -93 % of total cumulative surface area and the toluene vapor equilibrium adsorption capacities were in the range of 350 - 390mg/g. Activated carbons having larger toluene adsorption capacity than the compared activated carbons had relatively pores in the pore diameter range of $7-10{\AA}$ . Linear relationship between equilibrium adsorption capacity and cumulative sur- face area was in the diameter range of over $7{\AA}$ . It was thought that toluene vapor was relatively well adsorbed on surfaces of pores of over $7{\AA}$ .

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Available abstract

This study is to investigate the relationship between pore structures of activated carbons and adsorption characteristics of toluene vapor using dynamic adsorption method. The surface areas of below $10{\AA}$ in the pore diameter of activated carbons used in this experiment were in the range of 72 -93 % of total cumulative surface area and the toluene vapor equilibrium adsorption capacities were in the range of 350 - 390mg/g. Activated carbons having larger toluene adsorption capacity than the compared activated carbons had relatively pores in the pore diameter range of $7-10{\AA}$ . Linear relationship between equilibrium adsorption capacity and cumulative sur- face area was in the diameter range of over $7{\AA}$ . It was thought that toluene vapor was relatively well adsorbed on surfaces of pores of over $7{\AA}$ .

Key concepts: Adsorption, Toluene, Activated carbon, Chemical engineering, Carbon fibers, Chemistry, Specific surface area, Materials science

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