Complex Characteristic of Zircon from Granitoids of the Verkhneurmiysky Massif (Amur Region)

The study presents a complex characteristic of zircon from the Verkhneurmiysky intrusive series with Li-F granites. A wide range of morphological and chemical properties of zircon allowed us to obtain new information on the formation and alteration of zircon from biotite and zinnwaldite granitoids and to determine its features, which contribute to the correct definition of Li-F granites formed directly before the tin mineralization. The reviled trends of zircon morphology and composition evolution in the Verkhneurmiysky granites series are: the high-temperature morphotypes are followed by low-temperature ones with more complicated internal structure with secondary alteration zones, mineral inclusions, pores, and cracks; the increasing concentration of volatile (H2O, F), large ion lithophile (Cs, Sr), high field strength (Hf, Nb) and rare-earth elements with decreasing crystallization temperatures and the determining role of the fluid phase (predominantly, F) in the trace element accumulation. The composition of zircon cores in biotite and zinnwaldite granites is very similar. However, the zircon rims from zinnwaldite granites are much more enriched in trace elements compared to those from biotite granites. The first study of zircon from the Verkhneurmiysky granitoids provides new data on the formation and alteration conditions of granitoids, including zinnwaldite ones.