Theory of high-order harmonic generation from molecules by intense laser pulses

Abstract. We show that high-order harmonics generated from molecules by intense laser pulses can be expressed as the product of a returning electron wave packet and the photo-recombination cross section (PRCS) where the electron wave packet can be obtained from simple strong-field approximation (SFA) or from a companion atomic target. Using these wave packets but replacing the PRCS obtained from SFA or from the atomic target by the accurate PRCS from molecules, the resulting HHG spectra are shown to agree well with the benchmark results from direct numerical solution of the time-dependent Schrödinger equation, for the case of H + 2 in laser fields. The result illustrates that these powerful theoretical tools can be used for obtaining highorder harmonic spectra from molecules. More importantly, the results imply that the PRCS extracted from laser-induced HHG spectra can be used for time-resolved dynamic chemical imaging of transient molecules with temporal resolutions down to a few femtoseconds. PACS numbers: 42.65.Ky, 33.80.Rv Submitted to: J. Phys. BTheory of high-order harmonic generation from molecules by intense laser pulses 2