2018Strathprints: The University of Strathclyde institutional repository (University of Strathclyde)Open access

Relativistic properties of a molecule: energy, linear momentum, angular momentum and boost momentum to order $1/c^2$

Robert P. Cameron, Cotter, J. P.

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Abstract

We give an explicit and general description of the energy, linear momentum, angular momentum and boost momentum of a molecule to order $1/c^2$, where it necessary to take account of kinetic contributions made by the electrons and nuclei as well as electromagnetic contributions made by the intramolecular field. A wealth of interesting subtleties are encountered that are not seen at order $1/c^0$, including relativistic Hall shifts, anomalous velocities and hidden momenta. Some of these have well known analogues in solid state physics.

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We give an explicit and general description of the energy, linear momentum, angular momentum and boost momentum of a molecule to order $1/c^2$, where it necessary to take account of kinetic contributions made by the electrons and nuclei as well as electromagnetic contributions made by the intramolecular field. A wealth of interesting subtleties are encountered that are not seen at order $1/c^0$, including relativistic Hall shifts, anomalous velocities and hidden momenta. Some of these have well known analogues in solid state physics.

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Available abstract

We give an explicit and general description of the energy, linear momentum, angular momentum and boost momentum of a molecule to order $1/c^2$, where it necessary to take account of kinetic contributions made by the electrons and nuclei as well as electromagnetic contributions made by the intramolecular field. A wealth of interesting subtleties are encountered that are not seen at order $1/c^0$, including relativistic Hall shifts, anomalous velocities and hidden momenta. Some of these have well known analogues in solid state physics.

Key concepts: Physics, Kinetic energy, Momentum (technical analysis), Angular momentum, Angular momentum coupling, Electron, Order (exchange), Total angular momentum quantum number

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