Cryptic evidence for the former presence of lawsonite in blueschist and eclogite
Timothy Chapman, G. L. Clarke
Abstract
Timothy Chapman, G. L. Clarke
Abstract
Abstract Cryptic geochemical indicators of prograde lawsonite breakdown are established in basic and metasedimentary Eocene blueschist and eclogite in New Caledonia utilizing phase equilibria modelling and synchrotron X‐ray fluorescence mapping. Lawsonite–epidote‐bearing eclogite has garnet with concentric zones depleted in the LREE and MREE, and clinozoisite with high‐Sr rims, which geochemically record a prograde stage of lawsonite stability. These records persist in eclogite that now lacks lawsonite, and may be used to validate texturally based interpretations for prograde lawsonite stability. The compositional trends depend on extrinsic and intrinsic variables, including bulk rock composition, which determine the rock‐forming and accessory minerals that host Sr and the REEs. Distinct prograde reaction histories are recorded by two eclogite terranes in NE New Caledonia due to subtle distinctions in their protolith whole‐rock compositions.
OpenAlex reports 10 citations for this work. Citation counts describe recorded attention and do not establish research quality.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
Abstract Cryptic geochemical indicators of prograde lawsonite breakdown are established in basic and metasedimentary Eocene blueschist and eclogite in New Caledonia utilizing phase equilibria modelling and synchrotron X‐ray fluorescence mapping. Lawsonite–epidote‐bearing eclogite has garnet with concentric zones depleted in the LREE and MREE, and clinozoisite with high‐Sr rims, which geochemically record a prograde stage of lawsonite stability. These records persist in eclogite that now lacks lawsonite, and may be used to validate texturally based interpretations for prograde lawsonite stability. The compositional trends depend on extrinsic and intrinsic variables, including bulk rock composition, which determine the rock‐forming and accessory minerals that host Sr and the REEs. Distinct prograde reaction histories are recorded by two eclogite terranes in NE New Caledonia due to subtle distinctions in their protolith whole‐rock compositions.
Key concepts: Lawsonite, Eclogite, Blueschist, Geology, Geochemistry, Glaucophane, Phengite, Epidote