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2020•Chemical ScienceOpen access

trans -Hydroboration–oxidation products in Δ 5 -steroids via a hydroboration- retro -hydroboration mechanism

J. Ciciolil Hilario-Martínez, Fernando Murillo, Jair García-Méndez, Eugenia Dzib, Jesús Sandoval-Ramı́rez, Miguel‐Ángel Muñoz‐Hernández, Sylvain Bernès, László Kürti, Fernanda Duarte, Gabriel Merino, María A. Fernández‐Herrera

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Abstract

-structure and the subsequent hydroboration by the β-face. Besides, the corresponding Markovnikov type products have been isolated in synthetically useful yields. The behavior of the reaction under a range of temperatures is also investigated.

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-structure and the subsequent hydroboration by the β-face. Besides, the corresponding Markovnikov type products have been isolated in synthetically useful yields. The behavior of the reaction under a range of temperatures is also investigated.

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Available abstract

-structure and the subsequent hydroboration by the β-face. Besides, the corresponding Markovnikov type products have been isolated in synthetically useful yields. The behavior of the reaction under a range of temperatures is also investigated.

Key concepts: Hydroboration, Chemistry, Stereochemistry, Organic chemistry, Catalysis

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