Preparation and facile addition reactions of iminium salts derived from amino ketene silyl acetal and amino silyl enol ether
Makoto Shimizu, Shingo Hata, Koichi Kondo, Kazuhiro Murakami, Isao Mizota, Yusong Zhu
Abstract
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Makoto Shimizu, Shingo Hata, Koichi Kondo, Kazuhiro Murakami, Isao Mizota, Yusong Zhu
Abstract
Open-access reader
reactions with silyl enol ethers in good yields, new iminium salts are also prepared by the oxidation of amino silyl enol ethers. They undergo facile addition reaction with various nucleophiles to give α-amino ketone derivatives in good yields.
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reactions with silyl enol ethers in good yields, new iminium salts are also prepared by the oxidation of amino silyl enol ethers. They undergo facile addition reaction with various nucleophiles to give α-amino ketone derivatives in good yields.
Key concepts: Ketene, Iminium, Silylation, Enol, Chemistry, Nucleophile, Acetal, Silyl enol ether