Dynamic covalent synthesis of [2]- and [3]rotaxanes both in solution and on solid supports
Rafael Da Silva Rodrigues, David L. Marshall, John C. McMurtrie, Kathleen M. Mullen
Abstract
Rafael Da Silva Rodrigues, David L. Marshall, John C. McMurtrie, Kathleen M. Mullen
Abstract
Here we demonstrate the application of a dynamic covalent chemistry methodology for the synthesis of [2]- and [3]-rotaxanes not only in solution, but also on solid supports with 65% rotaxane functionalisation of the polymer resins observed.
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Here we demonstrate the application of a dynamic covalent chemistry methodology for the synthesis of [2]- and [3]-rotaxanes not only in solution, but also on solid supports with 65% rotaxane functionalisation of the polymer resins observed.
Key concepts: Chemistry, Rotaxane, Dynamic covalent chemistry, Covalent bond, Polymer, Polymer chemistry, Catenane, Nanotechnology