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2013•Journal of Inorganic and Organometallic Polymers and MaterialsOpen access

Synthesis, Crystal Structure and Luminescent Property of a New Two-Dimensional Zn(II) Coordination Polymer Based on Oxalic Acid and 1,4-Bis(imidazol-1-ylmethyl)-benzene

Qing-Wei Wang, Xiaofei Qi, Xiumei Li, Jian-Ye Ji, Yan-Ling Niu, Bo Liu

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Abstract

A new Zn(II) coordination polymer based on oxalic acid and 1,4-bis(imidazol-1-ylmethyl)benzene (bix), namely, [Zn(C 2 O 4 )(bix)] n ( 1 ), has been successfully synthesized under hydrothermal conditions. Its structure has been determined by single crystal X-ray diffraction analysis, elemental analyses and IR spectroscopy. Compound 1 shows a two-dimensional (2D) layer structure. The intermolecular C–H···O interactions extend the compound 1 into 3D supramolecular architectures and play an important role in stabilizing compound 1 . In addition, the luminescent property of the compound has also been investigated in solid state at room temperature.

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A new Zn(II) coordination polymer based on oxalic acid and 1,4-bis(imidazol-1-ylmethyl)benzene (bix), namely, [Zn(C 2 O 4 )(bix)] n ( 1 ), has been successfully synthesized under hydrothermal conditions. Its structure has been determined by single crystal X-ray diffraction analysis, elemental analyses and IR spectroscopy. Compound 1 shows a two-dimensional (2D) layer structure. The intermolecular C–H···O interactions extend the compound 1 into 3D supramolecular architectures and play an important role in stabilizing compound 1 . In addition, the luminescent property of the compound has also been investigated in solid state at room temperature.

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Available abstract

A new Zn(II) coordination polymer based on oxalic acid and 1,4-bis(imidazol-1-ylmethyl)benzene (bix), namely, [Zn(C 2 O 4 )(bix)] n ( 1 ), has been successfully synthesized under hydrothermal conditions. Its structure has been determined by single crystal X-ray diffraction analysis, elemental analyses and IR spectroscopy. Compound 1 shows a two-dimensional (2D) layer structure. The intermolecular C–H···O interactions extend the compound 1 into 3D supramolecular architectures and play an important role in stabilizing compound 1 . In addition, the luminescent property of the compound has also been investigated in solid state at room temperature.

Key concepts: Oxalic acid, Luminescence, Benzene, Coordination polymer, Intermolecular force, Supramolecular chemistry, Crystal structure, Crystallography

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Synthesis, Crystal Structure and Luminescent Property of a New Two-Dimensional Zn(II) Coordination Polymer Based on Oxalic Acid and 1,4-Bis(imidazol-1-ylmethyl)-benzene — Research Paper | ScholarLens