2020•Chemical CommunicationsOpen access

Thiocyanate complexes of the lanthanides, Am and Cm

Richard E. Wilson, Tyler J. Carter, Matthieu Autillo, Samantha Stegman

Abstract

The synthesis and single crystal structures of Am(iii) and Cm(iii) thiocyanate complexes are reported along with an isostructural series of lanthanide thiocyanate complexes. Because the complexes are isostructural, a comparative study of the metal-thiocyanate bonds was conducted using Raman spectroscopy indicating very similar and electrostatic metal-ligand interactions.

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Key concepts: Lanthanide, Actinide, Thiocyanate, Chemistry, Inorganic chemistry, Ion, Organic chemistry