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2020•Chemistry - A European JournalRequires access

Long‐Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin–Calixarene Assemblies

Massimiliano Gaeta, Giuseppe Sortino, Rosalba Randazzo, Ilenia Pisagatti, Anna Notti, Maria Elena Fragalà, Melchiorre F. Parisi, Alessandro D’Urso, Roberto Purrello

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Abstract

The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long-range electronic communication.

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What this paper is about

The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long-range electronic communication.

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Available abstract

The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long-range electronic communication.

Key concepts: Calixarene, Porphyrin, Supramolecular chemistry, Chemistry, Non-covalent interactions, Combinatorial chemistry, Stereochemistry, Nanotechnology

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Long‐Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin–Calixarene Assemblies — Research Paper | ScholarLens