A new hypervalent iodine( iii / v ) oxidant and its application to the synthesis of 2 H -azirines
Guangtao Zhang, Yuanxun Ethan Wang, Jun Xu, Jiyun Sun, Fengxia Sun, Yilin Zhang, Chenglin Zhang, Yunfei Du
Abstract
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Guangtao Zhang, Yuanxun Ethan Wang, Jun Xu, Jiyun Sun, Fengxia Sun, Yilin Zhang, Chenglin Zhang, Yunfei Du
Abstract
Open-access reader
The reaction of o -nitroiodobenzene and m CPBA in AcOH was found to afford a novel hypervalent iodine compound which both iodine( iii ) and iodine( v ) moieties coexist. This new reagent is proved to be effective in realizing the synthesis of 2 H -azirines.
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The reaction of o -nitroiodobenzene and m CPBA in AcOH was found to afford a novel hypervalent iodine compound which both iodine( iii ) and iodine( v ) moieties coexist. This new reagent is proved to be effective in realizing the synthesis of 2 H -azirines.
Key concepts: Hypervalent molecule, Iodine, Chemistry, Reagent, Combinatorial chemistry, Stereochemistry, Organic chemistry