2019•Chemical ScienceOpen access

A new hypervalent iodine( iii / v ) oxidant and its application to the synthesis of 2 H -azirines

Guangtao Zhang, Yuanxun Ethan Wang, Jun Xu, Jiyun Sun, Fengxia Sun, Yilin Zhang, Chenglin Zhang, Yunfei Du

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Abstract

The reaction of o -nitroiodobenzene and m CPBA in AcOH was found to afford a novel hypervalent iodine compound which both iodine( iii ) and iodine( v ) moieties coexist. This new reagent is proved to be effective in realizing the synthesis of 2 H -azirines.

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The reaction of o -nitroiodobenzene and m CPBA in AcOH was found to afford a novel hypervalent iodine compound which both iodine( iii ) and iodine( v ) moieties coexist. This new reagent is proved to be effective in realizing the synthesis of 2 H -azirines.

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Available abstract

The reaction of o -nitroiodobenzene and m CPBA in AcOH was found to afford a novel hypervalent iodine compound which both iodine( iii ) and iodine( v ) moieties coexist. This new reagent is proved to be effective in realizing the synthesis of 2 H -azirines.

Key concepts: Hypervalent molecule, Iodine, Chemistry, Reagent, Combinatorial chemistry, Stereochemistry, Organic chemistry

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