2019•Materials Research ExpressOpen access

Improvement of high-temperature oxidation resistance of γ-TiAl intermetallic alloy by YSZ-NiCoCrAlY coating using APS process

Saeed Nouri, Saeid Sahmani, M Asayesh, M.M. Aghdam

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Abstract

As an important class of high temperature structural materials, γ-TiAl intermetallic alloys have demonstrated unique mechanical characteristics which can be considered as essential payoffs for industrial gas turbines and other applications.In the present investigation, the γ-TiAl alloy with chemical composition of Ti-48Al-2Nb-2Cr (at%) is put to use as the substrate material.Two different coatings are then employed namely as a single-layer coating applied via Ni-based powder of AMDRY 365-2 [NiCoCrAlY] and a two-layered TBC coating consisted of a ceramic top coat of Yttria-stabilized zirconia (YSZ) and a metallic bond coat of NiCoCrAlY using atmospheric plasma spraying (APS) process at  2000 C. A comprehensive microstructural analysis as well as the isothermal oxidation resistance is performed for the both coated intermetallic samples at  1000 C. It is found that for the two-layered thermal barrier coating (TBC) coating, there are the dominant compounds which include ZrO 2 oxide with a little amount of Y 2 O 3 oxide.It is indicated that the presence of these oxides has a substantial influence on the high temperature oxidation resistance of the formed TBC coating on the γ-TiAl alloy.Moreover, it is shown that the best high temperature oxidation resistance can be acquired via the two-layered TBC coating on the intermetallic substrate of γ-TiAl.

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As an important class of high temperature structural materials, γ-TiAl intermetallic alloys have demonstrated unique mechanical characteristics which can be considered as essential payoffs for industrial gas turbines and other applications.In the present investigation, the γ-TiAl alloy with chemical composition of Ti-48Al-2Nb-2Cr (at%) is put to use as the substrate material.Two different coatings are then employed namely as a single-layer coating applied via Ni-based powder of AMDRY 365-2 [NiCoCrAlY] and a two-layered TBC coating consisted of a ceramic top coat of Yttria-stabilized zirconia (YSZ) and a metallic bond coat of NiCoCrAlY using atmospheric plasma spraying (APS) process at  2000 C. A comprehensive microstructural analysis as well as the isothermal oxidation resistance is performed for the both coated intermetallic samples at  1000 C. It is found that for the two-layered thermal barrier coating (TBC) coating, there are the dominant compounds which include ZrO 2 oxide with a little amount of Y 2 O 3 oxide.It is indicated that the presence of these oxides has a substantial influence on the high temperature oxidation resistance of the formed TBC coating on the γ-TiAl alloy.Moreover, it is shown that the best high temperature oxidation resistance can be acquired via the two-layered TBC coating on the intermetallic substrate of γ-TiAl.

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Available abstract

As an important class of high temperature structural materials, γ-TiAl intermetallic alloys have demonstrated unique mechanical characteristics which can be considered as essential payoffs for industrial gas turbines and other applications.In the present investigation, the γ-TiAl alloy with chemical composition of Ti-48Al-2Nb-2Cr (at%) is put to use as the substrate material.Two different coatings are then employed namely as a single-layer coating applied via Ni-based powder of AMDRY 365-2 [NiCoCrAlY] and a two-layered TBC coating consisted of a ceramic top coat of Yttria-stabilized zirconia (YSZ) and a metallic bond coat of NiCoCrAlY using atmospheric plasma spraying (APS) process at  2000 C. A comprehensive microstructural analysis as well as the isothermal oxidation resistance is performed for the both coated intermetallic samples at  1000 C. It is found that for the two-layered thermal barrier coating (TBC) coating, there are the dominant compounds which include ZrO 2 oxide with a little amount of Y 2 O 3 oxide.It is indicated that the presence of these oxides has a substantial influence on the high temperature oxidation resistance of the formed TBC coating on the γ-TiAl alloy.Moreover, it is shown that the best high temperature oxidation resistance can be acquired via the two-layered TBC coating on the intermetallic substrate of γ-TiAl.

Key concepts: Intermetallic, Materials science, Metallurgy, Alloy, Yttria-stabilized zirconia, Coating, Composite material, Ceramic

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