An overview of caprolactam synthesis
Rawesh Kumar, Sneha Shah, Prangya Paramita Das, Gami Girishkumar Bhagavanbhai, Ahmed Sadeq Al-Fatesh, Biswajit Chowdhury
Abstract
Rawesh Kumar, Sneha Shah, Prangya Paramita Das, Gami Girishkumar Bhagavanbhai, Ahmed Sadeq Al-Fatesh, Biswajit Chowdhury
Abstract
Caprolactam is the precursor of many industrial chemical productions as in nylon industry, plastic industry, paint industry, lysine synthesis and cross-linking for polyurethanes. The production of caprolactam has been focus much from last three decades among the scientific community to fulfill the industrial need under environment precautions. Herein a sequential and explanatory review broadly covering the transformation of a different substrate as cyclohexanone oxime, cyclohexanone, cyclohexanol, cyclohexane, and biorenewable sources into caprolactam is presented. For every substrate, a wide range of catalyst including homogeneous as well as the heterogeneous system has been deeply considered. This study will be helpful for developing alternative industrial route for production of caprolactam.
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Caprolactam is the precursor of many industrial chemical productions as in nylon industry, plastic industry, paint industry, lysine synthesis and cross-linking for polyurethanes. The production of caprolactam has been focus much from last three decades among the scientific community to fulfill the industrial need under environment precautions. Herein a sequential and explanatory review broadly covering the transformation of a different substrate as cyclohexanone oxime, cyclohexanone, cyclohexanol, cyclohexane, and biorenewable sources into caprolactam is presented. For every substrate, a wide range of catalyst including homogeneous as well as the heterogeneous system has been deeply considered. This study will be helpful for developing alternative industrial route for production of caprolactam.
Key concepts: Caprolactam, Cyclohexane, Cyclohexanone oxime, Cyclohexanone, Beckmann rearrangement, Homogeneous, Substrate (aquarium), Pyrazolones