ChemInform Abstract: Metalloporphyrin‐Mediated Radical Cycloadditions of p‐Cyano‐N,N‐dimethylaniline.
C. M. DICKEN, F.‐L. LU, Thomas C. Bruice
Abstract
C. M. DICKEN, F.‐L. LU, Thomas C. Bruice
Abstract
Abstract The Baldwin metalloporphyrin (III) mediates the reaction between 4‐cyano‐dimethylaniline N‐oxide (I) and tetramethylethylene (II), yielding the epoxide (V), the amine (IV), and the tetrahydroquinoline (VI).
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Abstract The Baldwin metalloporphyrin (III) mediates the reaction between 4‐cyano‐dimethylaniline N‐oxide (I) and tetramethylethylene (II), yielding the epoxide (V), the amine (IV), and the tetrahydroquinoline (VI).
Key concepts: Chemistry, Dimethylaniline, Medicinal chemistry, Photochemistry