ChemInform Abstract: Triazole—Gold Promoted Intermolecular Propargyl Alcohol Addition to Alkyne: The Reaction Cascade Toward Substituted Allenes.
Seyedmorteza Hosseyni, Shengtao Ding, Yijin Su, Novruz G. Akhmedov, Xiaodong Shi
Abstract
Seyedmorteza Hosseyni, Shengtao Ding, Yijin Su, Novruz G. Akhmedov, Xiaodong Shi
Abstract
Abstract Au‐catalyzed intermolecular addition of propargyl alcohols (I) to alkynes (II) affords intermediate vinyl ethers, which in turn undergo [3,3]‐sigmatropic rearrangement towards substituted allenes (III).
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Abstract Au‐catalyzed intermolecular addition of propargyl alcohols (I) to alkynes (II) affords intermediate vinyl ethers, which in turn undergo [3,3]‐sigmatropic rearrangement towards substituted allenes (III).
Key concepts: Chemistry, Propargyl, Propargyl alcohol, Alkyne, Intermolecular force, Cascade, Alcohol, Cascade reaction