2016•ChemInformRequires access

ChemInform Abstract: Triazole—Gold Promoted Intermolecular Propargyl Alcohol Addition to Alkyne: The Reaction Cascade Toward Substituted Allenes.

Seyedmorteza Hosseyni, Shengtao Ding, Yijin Su, Novruz G. Akhmedov, Xiaodong Shi

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Abstract

Abstract Au‐catalyzed intermolecular addition of propargyl alcohols (I) to alkynes (II) affords intermediate vinyl ethers, which in turn undergo [3,3]‐sigmatropic rearrangement towards substituted allenes (III).

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What this paper is about

Abstract Au‐catalyzed intermolecular addition of propargyl alcohols (I) to alkynes (II) affords intermediate vinyl ethers, which in turn undergo [3,3]‐sigmatropic rearrangement towards substituted allenes (III).

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Available abstract

Abstract Au‐catalyzed intermolecular addition of propargyl alcohols (I) to alkynes (II) affords intermediate vinyl ethers, which in turn undergo [3,3]‐sigmatropic rearrangement towards substituted allenes (III).

Key concepts: Chemistry, Propargyl, Propargyl alcohol, Alkyne, Intermolecular force, Cascade, Alcohol, Cascade reaction

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ChemInform Abstract: Triazole—Gold Promoted Intermolecular Propargyl Alcohol Addition to Alkyne: The Reaction Cascade Toward Substituted Allenes. — Research Paper | ScholarLens