ChemInform Abstract: Diastereo‐ and Enantioselective Iridium Catalyzed Carbonyl (α‐Cyclopropyl)allylation via Transfer Hydrogenation.
Ryosuke Tsutsumi, Suckchang Hong, Michael J. Krische
Abstract
Ryosuke Tsutsumi, Suckchang Hong, Michael J. Krische
Abstract
Abstract Using the chiral precatalyst modified by SEGPHOS, the carbonyl α‐(cyclopropyl)allylation is reached with similar facility from alcohol or aldehyde oxidation levels of the substrates.
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Abstract Using the chiral precatalyst modified by SEGPHOS, the carbonyl α‐(cyclopropyl)allylation is reached with similar facility from alcohol or aldehyde oxidation levels of the substrates.
Key concepts: Chemistry, Iridium, Transfer hydrogenation, Enantioselective synthesis, Catalysis, Asymmetric hydrogenation, Organic chemistry, Medicinal chemistry