ChemInform Abstract: Regiospecific Tetrahydropyran‐3‐one Enolates. Synthesis and Reactivity of Silyl Enol Ether Derivatives.
Paul Cox, Mary F. Mahon, K.C. Molloy, Simon Lister, Timothy Gallagher
Abstract
Paul Cox, Mary F. Mahon, K.C. Molloy, Simon Lister, Timothy Gallagher
Abstract
Abstract The silyl enol ether (VI), derived from dihydropyran (I), is coupled with various electrophilic moieties in the presence of Lewis acids, e.g. tin or titanium tetrachloride or trimethylsilyl triflate.
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Abstract The silyl enol ether (VI), derived from dihydropyran (I), is coupled with various electrophilic moieties in the presence of Lewis acids, e.g. tin or titanium tetrachloride or trimethylsilyl triflate.
Key concepts: Chemistry, Titanium tetrachloride, Silylation, Dihydropyran, Tetrahydropyran, Enol, Trifluoromethanesulfonate, Trimethylsilyl