Yûji Matsuya, Kousuke Hayashi, Hideo Nemoto
Abstract
A new reaction of propiolates and aldehydes mediated by DABCO analogous to the Baylis-Hillman reaction is described. This reaction provided novel beta-functionalized Baylis-Hillman products and a new methodology for the generation of alkylidene carbene species.
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A new reaction of propiolates and aldehydes mediated by DABCO analogous to the Baylis-Hillman reaction is described. This reaction provided novel beta-functionalized Baylis-Hillman products and a new methodology for the generation of alkylidene carbene species.
Key concepts: DABCO, Chemistry, Baylis–Hillman reaction, Carbene, Organic chemistry, Combinatorial chemistry, Reaction conditions, Adduct