ChemInform Abstract: Chemistry of Aryl‐Lead(IV) Tricarboxylates. Reaction with Vinylogous β‐Keto Esters.
Darren J. Ackland, JT Pinhey
Abstract
Darren J. Ackland, JT Pinhey
Abstract
Abstract Hagemann's ester (IIa) and the demethyl analogue (VI) (in equilibrium with the isomer (VII)) in Py/CHCl3 or in DMSO undergo regiospecific arylation at C‐1 with aryl‐lead triacetates (I) to yield (III) and (VIII), respectively.
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Abstract Hagemann's ester (IIa) and the demethyl analogue (VI) (in equilibrium with the isomer (VII)) in Py/CHCl3 or in DMSO undergo regiospecific arylation at C‐1 with aryl‐lead triacetates (I) to yield (III) and (VIII), respectively.
Key concepts: Chemistry, Yield (engineering), Aryl, Lead (geology), Organic chemistry, Medicinal chemistry, Alkyl, Geomorphology