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ChemInform Abstract: Mononuclear Manganese(IV) Complexes of Hydroxyl‐Rich Schiff Base Ligands.

D.P. Kessissoglou, X. Li, William M. Butler, V.L. Pecoraro

Abstract

Abstract Hydroxyl‐rich Schiff base ligands prepared from salicylaldehyde (II) and appropriate hydroxyl‐rich prim. amines such as (II) react with Mn(III) acetate (III) or Mn(II) chloride in basic solution of DMF or MeOH with air oxidation generating the monomeric stable Mn(IV) complexes (IV) and (V).

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Available abstract

Key concepts: Chemistry, Salicylaldehyde, Schiff base, Manganese, Chloride, Monomer, Polymer chemistry, Base (topology)