ChemInform Abstract: Synthesis, Structure, and Reactivity of Trimethylphosphine‐Zirconocene Thioaldehyde Complexes.
Stephen L. Buchwald, Ralph B. Nielsen, John C. Dewan
Abstract
Stephen L. Buchwald, Ralph B. Nielsen, John C. Dewan
Abstract
Abstract The zirconocene thioaldehyde complexes (IV), which are stabilized by coordination of a trimethylphosphine ligand, are prepared simply by treatment of (I) with a thiol (II) and heating the resulting compounds (III) in the presence of trimethylphosphine.
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Abstract The zirconocene thioaldehyde complexes (IV), which are stabilized by coordination of a trimethylphosphine ligand, are prepared simply by treatment of (I) with a thiol (II) and heating the resulting compounds (III) in the presence of trimethylphosphine.
Key concepts: Trimethylphosphine, Chemistry, Reactivity (psychology), Ligand (biochemistry), Medicinal chemistry, Organic chemistry, Molecule, Receptor