ChemInform Abstract: Triplex‐Catalyzed Diels‐Alder and (2 + 2)Cycloaddition Reactions of Enol Ethers and Ketene Acetals.
Nihat Akbulut, Gary B. Schuster
Abstract
Nihat Akbulut, Gary B. Schuster
Abstract
Abstract Cyclohexadiene (I) undergoes photochemical reaction with the silyl enol ethers (IIa) and (IIb) or the ketene acetal (IIc) in the presence of sensitizers such as 9,10‐dicyanoanthracene to form the bicyclooctenes (III) and (IV).
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Abstract Cyclohexadiene (I) undergoes photochemical reaction with the silyl enol ethers (IIa) and (IIb) or the ketene acetal (IIc) in the presence of sensitizers such as 9,10‐dicyanoanthracene to form the bicyclooctenes (III) and (IV).
Key concepts: Ketene, Chemistry, Enol, Acetal, Silylation, Cycloaddition, Catalysis, Enol ether