ChemInform Abstract: Synthesis, Structure, and Fluxional Behavior of Di‐tert‐butylcyclopentadienyl Compounds of Group 15 Elements.
Sultan T. Abu‐Orabi, P. JUTZI
Abstract
Sultan T. Abu‐Orabi, P. JUTZI
Abstract
Abstract 1,3‐Di‐tert‐butylcyclopentadiene (I) is lithiated to give the intermediate (III) which reacts with the trichlorides (IV), yielding the cyclopentadienyldichlorophosphane (Va), and the analogous arsane (Vb) and stibane (Vc).
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Abstract 1,3‐Di‐tert‐butylcyclopentadiene (I) is lithiated to give the intermediate (III) which reacts with the trichlorides (IV), yielding the cyclopentadienyldichlorophosphane (Va), and the analogous arsane (Vb) and stibane (Vc).
Key concepts: Chemistry, Group (periodic table), Stereochemistry, Medicinal chemistry, Organic chemistry