2015•SynlettRequires access

Recent Development in N-Auxilixary-Assisted Intramolecular Amination for Amine Substrates

Yingsheng Zhao, Chao Wang, Jian Han

Abstract

Direct coupling of N–H with C–H has aroused great attention in the last decades; during which the directing-group-assisted intramolecular C–N bond formation via transition metal has been achieved significant progress. Herein, we highlight the recent development in the directing-group-assisted intramolecular amination for amine substrates to build the important N-containing heterocyclic compounds. 1 Introduction 2 Triflamide-Promoted Intramolecular Amination 3 Picolinamide-Assisted Intramolecular Amination 4 Palladium-Catalyzed Intramolecular Amination under Assistance of Oxalyl Amide 5 Conclusion

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Available abstract

Key concepts: Intramolecular force, Amination, Chemistry, Amide, Amine gas treating, Palladium, Combinatorial chemistry, Reductive amination