ChemInform Abstract: Pinacol Boronates by Direct Arene Borylation with Borenium Cations.
Alessandro Del Grosso, Paul J. Singleton, C.A. Muryn, Michael J. Ingleson
Abstract
Alessandro Del Grosso, Paul J. Singleton, C.A. Muryn, Michael J. Ingleson
Abstract
Abstract It is demonstrated, that catecholato ligated borenium cations, generated in solution from CCB, react as electrophiles with activated arenes and hetarenes to give a variety of pinacol boronates after quenching with pinacol.
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Abstract It is demonstrated, that catecholato ligated borenium cations, generated in solution from CCB, react as electrophiles with activated arenes and hetarenes to give a variety of pinacol boronates after quenching with pinacol.
Key concepts: Pinacol, Chemistry, Borylation, Electrophile, Quenching (fluorescence), Combinatorial chemistry, Medicinal chemistry, Organic chemistry