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ALANINE/CHLOROCHROMIC ACID/SILICA GEL: AN EFFICIENT AND SELECTIVE REAGENT FOR THE OXIDATION OF ORGANIC FUNCTIONAL GROUPS

Peyman Salehi, Mohammad Mehdi Khodaei, Amin Rostami

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Abstract

Alanine/chlorochromic acid/silica gel is a new and selective reagent for the efficient oxidation of sulfides, thiols, oximes, and alcohols. Oxidation of sulfides is solvent dependent. In chloroform at room temperature sulfoxides are formed as the major products, while in carbon tetrachloride or under solvent-free conditions solfones are produced in good-to-excellent yields.

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What this paper is about

Alanine/chlorochromic acid/silica gel is a new and selective reagent for the efficient oxidation of sulfides, thiols, oximes, and alcohols. Oxidation of sulfides is solvent dependent. In chloroform at room temperature sulfoxides are formed as the major products, while in carbon tetrachloride or under solvent-free conditions solfones are produced in good-to-excellent yields.

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Available abstract

Alanine/chlorochromic acid/silica gel is a new and selective reagent for the efficient oxidation of sulfides, thiols, oximes, and alcohols. Oxidation of sulfides is solvent dependent. In chloroform at room temperature sulfoxides are formed as the major products, while in carbon tetrachloride or under solvent-free conditions solfones are produced in good-to-excellent yields.

Key concepts: Reagent, Chloroform, Chemistry, Silica gel, Carbon tetrachloride, Solvent, Alanine, Organic chemistry

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ALANINE/CHLOROCHROMIC ACID/SILICA GEL: AN EFFICIENT AND SELECTIVE REAGENT FOR THE OXIDATION OF ORGANIC FUNCTIONAL GROUPS — Research Paper | ScholarLens