ChemInform Abstract: Asymmetric Synthesis of Chiral Amines via Nucleophilic Addition to Ferrocenylalkyl Substituted Imines.
Dorothy M. David, Leon A. P. Kane‐Maguire, Stephen G. Pyne
Abstract
Dorothy M. David, Leon A. P. Kane‐Maguire, Stephen G. Pyne
Abstract
Abstract The isomerically pure imine (III) undergoes nucleophilic attack to give the diastereomeric compounds (V) and (VI) from which the amine (VIII) (yield not given) is released and the chiral ferrocenyl auxiliary is regenerated as the acetate (IX).
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Abstract The isomerically pure imine (III) undergoes nucleophilic attack to give the diastereomeric compounds (V) and (VI) from which the amine (VIII) (yield not given) is released and the chiral ferrocenyl auxiliary is regenerated as the acetate (IX).
Key concepts: Chemistry, Diastereomer, Imine, Nucleophile, Nucleophilic addition, Yield (engineering), Amine gas treating, Chiral auxiliary