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ChemInform Abstract: The Generation and Use of a Masked α‐Acyl Cation in Aromatic Substitution Reactions. Ag+‐Induced Reactions of 3‐(Bromomethyl)‐5,6‐dihydro‐1,4,2‐dioxazine Derivatives.

Shimon Shatzmiller, Sorin Bercovici

Abstract

Abstract Bromination of the alkyldihydrodioxazines (I) with N‐bromosuccinimide in the presence of benzoyl peroxide yields the bromoalkyl derivatives (II) which are substituted to produce the azides (IV) and fluorides (VI).

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Key concepts: Chemistry, Halogenation, Benzoyl peroxide, Medicinal chemistry, Substitution reaction, Substitution (logic), Electrophilic aromatic substitution, Organic chemistry