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ChemInform Abstract: Organosulfide Group Transfer Reactions of Transition‐Metal Carbonyl Radicals: Electronic and Steric Effects.

Kyu‐Jung Lee, Theodore L. Brown

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Abstract

Abstract The initial product for each photochemical reaction shown in the scheme is RSM(CO)4L (L: CO, PMe3) formed by RS group transfer from (II) to the M(CO)4L· radical generated by photolysis.

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What this paper is about

Abstract The initial product for each photochemical reaction shown in the scheme is RSM(CO)4L (L: CO, PMe3) formed by RS group transfer from (II) to the M(CO)4L· radical generated by photolysis.

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Available abstract

Abstract The initial product for each photochemical reaction shown in the scheme is RSM(CO)4L (L: CO, PMe3) formed by RS group transfer from (II) to the M(CO)4L· radical generated by photolysis.

Key concepts: Chemistry, Radical, Steric effects, Photochemistry, Photodissociation, Transition metal, Group (periodic table), Electronic effect

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ChemInform Abstract: Organosulfide Group Transfer Reactions of Transition‐Metal Carbonyl Radicals: Electronic and Steric Effects. — Research Paper | ScholarLens