1990•Liebigs Annalen der ChemieRequires access

Synthesis and properties of the enantiomers of the two artificial fragrances lilial and methylundecanal

Dieter Enders, Hubert Dyker

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Abstract

Abstract The enantiomers of the two artificial fragrances 3‐(4‐tert‐butylphenyl)‐2‐methylpropanal (lilial) and 2‐methylundecanal are synthesized with high enantiomeric purity using the SAMP/RAMP hydrazone method. The enantiomeric excesses are determined by HPLC via the corresponding SASP hydrazones. The olfactorial qualities of the enantiomers are described.

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Abstract The enantiomers of the two artificial fragrances 3‐(4‐tert‐butylphenyl)‐2‐methylpropanal (lilial) and 2‐methylundecanal are synthesized with high enantiomeric purity using the SAMP/RAMP hydrazone method. The enantiomeric excesses are determined by HPLC via the corresponding SASP hydrazones. The olfactorial qualities of the enantiomers are described.

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Available abstract

Abstract The enantiomers of the two artificial fragrances 3‐(4‐tert‐butylphenyl)‐2‐methylpropanal (lilial) and 2‐methylundecanal are synthesized with high enantiomeric purity using the SAMP/RAMP hydrazone method. The enantiomeric excesses are determined by HPLC via the corresponding SASP hydrazones. The olfactorial qualities of the enantiomers are described.

Key concepts: Enantiomer, Chemistry, Hydrazone, High-performance liquid chromatography, Chromatography, Stereochemistry

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