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ChemInform Abstract: Stereochemistry of Conjugate Addition to 4‐ and 5‐Substituted α,β‐Unsaturated δ‐Lactones.

Ian Fleming, N. Laxma Reddy, Ken Takaki, Anne Ware

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Abstract

Abstract The unsaturated lactones (I) and (X) and the unsaturated lactam (XIII) undergo conjugate addition reaction with the phenyldimethylsilylcuprate (II) or the Grignard reagent (VII) to give the trans‐products (III), (VIIIa), (XI), and (XIV).

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What this paper is about

Abstract The unsaturated lactones (I) and (X) and the unsaturated lactam (XIII) undergo conjugate addition reaction with the phenyldimethylsilylcuprate (II) or the Grignard reagent (VII) to give the trans‐products (III), (VIIIa), (XI), and (XIV).

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Available abstract

Abstract The unsaturated lactones (I) and (X) and the unsaturated lactam (XIII) undergo conjugate addition reaction with the phenyldimethylsilylcuprate (II) or the Grignard reagent (VII) to give the trans‐products (III), (VIIIa), (XI), and (XIV).

Key concepts: Chemistry, Conjugate, Reagent, Addition reaction, Stereochemistry, Medicinal chemistry, Organic chemistry, Catalysis

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ChemInform Abstract: Stereochemistry of Conjugate Addition to 4‐ and 5‐Substituted α,β‐Unsaturated δ‐Lactones. — Research Paper | ScholarLens