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ChemInform Abstract: Reactions of Trimethylphosphine‐Pentaboranes with Trityl Cation. Formation of Octahydrobis(trimethylphosphine)pentaboron(1+) and Octahydro(trimethylphosphine)pentaboron(1+) Cations.

Mitsuaki Kameda, Goji Kodama

Abstract

Abstract The title cations are obtained by abstracting a hydride ion from the trimethylphosphine adducts (I) and (III) of pentaborane(9), isolated as their at room temp. fairly stable tetrafluoroborates (IIa) and (IV), and characterized by NMR (11B, 1H, 31P) spectra.

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Key concepts: Trimethylphosphine, Chemistry, Adduct, Hydride, Medicinal chemistry, Organic chemistry, Molecule, Hydrogen