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ChemInform Abstract: THE CHEMISTRY OF MOLYBDENUM AND TUNGSTEN. PART 7. OXOMOLYBDENUM(V) AND OXOTUNGSTEN(V) COMPLEXES OF NEUTRAL AROMATIC SCHIFF‐BASE LIGANDS

Charles A. McAuliffe, F. P. MCCULLOUGH, Maxwell J. Parrott, Cynthia A. Rice, B. J. SAYLE, William Levason

Abstract

Abstract Die aufgezeigten Schiffschen Basen fungieren bei der Umsetzung mit Oxotrichloro‐bis‐[THF]‐Mo oder ‐W in Toluol/Methylenchlorid als neutrale, zweizähnige NN‐Liganden und bilden abhängig von der Kettenlänge Ydie monomeren mer‐Komplexe (I) oder Isomerengemische der ligandverbrückten dimeren Komplexe (ID und (III) (Y: ‐(CH2)5‐ ).

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Key concepts: Molybdenum, Chemistry, Tungsten, Polymer chemistry, Schiff base, Medicinal chemistry, Inorganic chemistry, Organic chemistry