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ChemInform Abstract: Remote Steric Effects on the Disproportionation/Recombination Ratio of Cumyl Radicals.

Karl R. Kopecky, Mei-Yuk Yeung

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Abstract

Abstract The disproportionation/combination ratio in the reaction between two di‐tert‐butyl‐cumyl radicals (II), generated by thermolysis of the diazene (I), is 0.21 at 60 °C in benzene.

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What this paper is about

Abstract The disproportionation/combination ratio in the reaction between two di‐tert‐butyl‐cumyl radicals (II), generated by thermolysis of the diazene (I), is 0.21 at 60 °C in benzene.

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Available abstract

Abstract The disproportionation/combination ratio in the reaction between two di‐tert‐butyl‐cumyl radicals (II), generated by thermolysis of the diazene (I), is 0.21 at 60 °C in benzene.

Key concepts: Disproportionation, Chemistry, Radical, Steric effects, Radical disproportionation, Benzene, Thermal decomposition, Photochemistry

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ChemInform Abstract: Remote Steric Effects on the Disproportionation/Recombination Ratio of Cumyl Radicals. — Research Paper | ScholarLens