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2005•ACS symposium seriesRequires access

SF 5 -Synthons: Pathways to Organic Derivatives of SF 6

Rolf W. Winter, Rozalia A. Dodean, Gary L. Gard

Open publisher page 31 citations

Abstract

In this review, the synthesis and use of the primary synthons SF 5 X (X = F, Cl, Br, SF 5 ) in forming organic derivatives of SF 6 will be described. We have found that using primary SF 5 X synthons, convenient pathways exist for preparing secondary synthons that include SF 5 - alkanes, alkenes, alkynes, iodides and aromatics. The primary synthons also offer pathways for preparing and studying the reactive SF 5 +, SF 6 -, and SF 5 · intermediates.

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What this paper is about

In this review, the synthesis and use of the primary synthons SF 5 X (X = F, Cl, Br, SF 5 ) in forming organic derivatives of SF 6 will be described. We have found that using primary SF 5 X synthons, convenient pathways exist for preparing secondary synthons that include SF 5 - alkanes, alkenes, alkynes, iodides and aromatics. The primary synthons also offer pathways for preparing and studying the reactive SF 5 +, SF 6 -, and SF 5 · intermediates.

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Available abstract

In this review, the synthesis and use of the primary synthons SF 5 X (X = F, Cl, Br, SF 5 ) in forming organic derivatives of SF 6 will be described. We have found that using primary SF 5 X synthons, convenient pathways exist for preparing secondary synthons that include SF 5 - alkanes, alkenes, alkynes, iodides and aromatics. The primary synthons also offer pathways for preparing and studying the reactive SF 5 +, SF 6 -, and SF 5 · intermediates.

Key concepts: Synthon, Primary (astronomy), Chemistry, Organic synthesis, Organic chemistry, Combinatorial chemistry, Catalysis, Physics

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